What is the best plastic for making molds?

08 Apr.,2024

 

Material selection plays an important part in just about every facet of the plastic injection molding process, so it’s critical not to overlook this step. Here, we’ll take a look at the “why” of material selection — how it affects your product and the manufacturing process — as well as the “what” — meaning, you’ll learn a bit about some of the most commonly used plastic injection molding materials, what their qualities are, and their functions.

The simple answer to the question of “why is material selection important for plastic injection molding?” is what we just mentioned — it factors into just about every aspect of the product development process. For instance:

End product

The material you use plays a role in the end function and performance of your product itself: choose the wrong material, and your product may not work properly. A more flexible resin isn’t suited to a function where rigidity and strength are required. More importantly, non-food grade or medical grade materials can present real health hazards and risks if used in food or medical functions.

Plastic injection molding process

Different resins have different qualities that play a role in the manufacturing process, like melting point, cooling point and viscosity. More complex molds may require a material that’s better able to reach all areas for full coverage, and different melting points and cooling points can help avert problems like sink and cavities in your product.

Budget

Knowing the requirements of your particular injection molding process (like mold design and complexity), as well as those of your end product, can help you choose a material with the qualities you need, at the lowest cost possible. Don’t end up paying a premium for material aspects and features that you don’t need.

Now that you know a few of the areas where material selection makes a difference, the following checklist can be a good reference point of factors you should consider:

  • Durometer (or hardness and flexibility)
  • Strength
  • Corrosion resistance
  • Heat resistance
  • Viscosity
  • Melting point
  • Cooling point
  • Cooling time
  • Thermoset versus thermoplastic (Thermoset plastics harden when heated, and retain their rigidity even when heated again. Thermoplastics harden when cooled, and are subject to softening or melting upon reheating.)
  • Color/appearance
  • Ability to have

    colorant added

    , if required
  • Reactivity with other material
  • Food grade, medical grade or other specification requirements

Now, let’s take a look at some of the most common resins used in plastic injection molding, as well as some of their qualities and optimal uses.

ABS: ABS is a very common thermoplastic that can be used for a wide variety of end products. It is relatively inexpensive and provides strong rigidity and resistance to breaking or shattering, even upon impact. It is also resistant to a number of acids and other corrosives, but not all of them. ABS is not suitable for food use, and it is flammable and shows poor resistance to sunlight. Aesthetically, ABS in its raw form appears white or translucent, although it can be colored using additives. ABS is found in applications like electronic casings, automotive components where shock resistance is important, and toys like Lego.

Acrylic: Frequently used to mimic the appearance of glass, acrylic is used in applications like sunglasses and display cases. Acrylic has a high hardness rating, making it exceptionally scratch resistant, and it is also highly resistant to breakage.

Epoxy: Epoxy is a thermoset resin that as such, offers extremely high strength, as well as resistance to heat and many chemicals after curing. It is important to note that the qualities of epoxy differ based on the curing (or hardening) agent used, so be sure to have a thorough understanding of your product’s end requirements before choosing epoxy as a plastic injection molding resin. Due to its high electrical insulation abilities, epoxy is frequently used in circuits and transistors. Epoxy can also be found in motor and transformer components, as well as in marine applications, such as plugs.

Polycarbonate (PC): Polycarbonate is a transparent thermoplastic that offers some of the strongest, most shatter-resistant construction available for plastic injection molded products. Polycarbonate is typically transparent in its raw form, and it is highly receptive to sterilization, making it well-suited for medical applications (although it may not be used for medical components intended for placement in the human body). While its strength and break resistance make polycarbonate a common choice in eyeglass lenses and some types of shatterproof or bulletproof glass, it is not very scratch resistant, and so will typically need to be treated or coated with a harder material after the injection molding process. Polycarbonate is also not especially resistant to repeated vibration or stress, as automotive or aerospace components would encounter, and should not be used for these applications.

Polyethylene (PE or PET): Polyethylene is a very strong thermoplastic with an extremely high melting point and a high viscosity. Thin-walled, high-strength applications are the ideal application for polyethylene, and it is also frequently found in disposable plastic water bottles. Polyethylene boasts a high viscosity that makes it well-suited for more complex molds; however, mold setup and cooling times can be longer. For applications where recycling is a concern, polyethylene is one of the best choices you can make.

Polypropylene (PP): Polypropylene is commonly used in consumer-packaged goods like water bottles, as well as household items like garbage cans, pails and flatware. It is also frequently used in living hinges and scientific lab supplies due to its shatter-resistant properties. With its low cost, high strength and flexibility, polypropylene is ideally suited to high-volume production runs, and works well even in complex molds due to its very high viscosity. Polypropylene is readily available in a clear raw form, although it is naturally opaque.

Polystyrene (PS): Polystyrene is best for plastic injection molding where budget is a concern; however, there are tradeoffs in strength and other qualities. If a break-resistant product is required, it’s best to look elsewhere. Polystyrene is ideal, however, for disposable products, and is frequently used in food packaging as well as single-use lab applications like petri dishes. Note that polystyrene does not offer high resistance to heat (only up to about 212 degrees Fahrenheit/100 degrees Celsius).

What are the most popular injection molding materials?

  1. Acrylic (PMMA)

  2. Acrylonitrile Butadiene Styrene (ABS)

  3. Nylon polyamide (PA)

  4. Polycarbonate (PC)

  5. Polyethylene (PE)

  6. Polyoxymethylene (POM)

  7. Polypropylene (PP)

  8. Polystyrene (PS)

  9. Thermoplastic Elastomer (TPE)

  10. Thermoplastic Polyurethane (TPU) 

We often get asked which plastic resins are the best choice for a client’s project. To answer it simply — there is no one answer for that. For each application, we can come up with suggested plastic materials, from which we choose one that works for you and your unique circumstances. 

The good news is that there are thousands of resins to choose from with similar – but not identical – properties, so you have many potential materials to choose from. So, to help you refine your search, we’ve prepared a short guide on the most common injection molding materials. Read on! 

Acrylic (PMMA)

Polymethyl methacrylate, better known as PMMA or simply acrylic, is a strong and clear thermoplastic that allows plenty of light to pass through.

Acrylic plastics have high tensile strength, so they can be load-bearing. They are also lightweight, and shatter-resistant, making them a good alternative for glass. Lastly, they are resistant to sunlight and weather, so they can be used outdoors.

However, acrylic won’t absorb odors, can become easily stained by greases and oils, and they scratch more readily. They also have a service temperature that’s too low for them to be used in industrial applications. They tend to stress crack under especially heavy loads, too. 

Common uses for acrylics are in window panels, greenhouses, solar panels, and other transparent materials for architectural and lighting projects.

Acrylonitrile Butadiene Styrene (ABS)

ABS is an engineering thermoplastic. It is an opaque and sturdy material. It’s best known for its enhanced strength and impact resistance.

The benefits of this plastic are that it is tough, inexpensive, and has good resistance to heat, grease, acids, and alkalis. It also has a shiny finish. 

However, unlike acrylic, this resin lacks strong resistance to sunlight or weather — making it a poor choice for outdoor products. ABS also creates plenty of smoke when burnt, and has poor resistance to friction and water. 

You can find ABS plastics used to make things like keyboard keys, plastic enclosures for outlets, protective headgear, and the like. It is also commonly used in automotive, consumer goods, sports equipment, and industrial fitting applications.

Nylon Polyamide (PA)

Also known as Nylon, this is a synthetic polyimide that can be challenging to work with in injection molding, as it is prone to shrinkage, which results in an inadequate filling. 

Nylon has a few advantages, however, such as high toughness, heat resistance, abrasion resistance, fatigue resistance, and noise dampening qualities. It’s also a good choice for high friction products. 

However, it does not have flame resistance — so it may burn quickly if not treated with a fire retardant. It also degrades easily under sunlight, but again, a UV stabilizer additive can be used to improve performance. 

It is often found in strong mechanical parts, casings, snap-fit closures, and threaded inserts. Nylon is also used to make things like toothbrushes, medical implants, and electrical connectors. 

Polycarbonate (PC)

PC plastics are tough resins, with similar properties to acrylic. However, PCs are more resilient over a wider temperature range. It also holds pigment well over time. 

PC plastics are very durable, and up to 250 times stronger than glass. It also has a very predictable and uniform shrinkage rate, so it’s good for projects that need precise dimensional control. It is also lightweight and has good optical properties.

However, it contains BPA, so this plastic cannot be used for food preparation or storage applications. It is also expensive to mold and does not offer scratch resistance.

You can find PC plastics in clear and tinted windows, diffusers, and clear molds for urethane and silicone casting.  

Polyethylene (PE)

PE is the most commonly used plastic in the world. It comes in three main types: high density (HDPE), low density (LDPE), and polyethylene terephthalate (PET). 

HDPE and LDPE plastics share the same high chemical and moisture resistance but differ in terms of hardness, optical transparency, melting point, flexibility, etc. These plastics are generally chosen for their good clarity. 

However, they are limited by poor sunlight resistance and poor resistance to high temperatures. HDPE also tends to be difficult to mold in thinner dimensions. LDPE, on the other hand, struggles to meet close tolerances. PET also absorbs too much water — requiring longer resin drying during production.

PE plastics are usually used to make things like milk bottles, water bottles, children’s toys, electronic wire, and some medical device components.

Polyoxymethylene (POM)

Also known as acetal, this is an engineering plastic that is typically recommended for parts that need low friction, high stiffness, and excellent integrity. This is because they have a good crystalline structure. POM resins are also naturally opaque, and white. 

When used in injection molding, POM features excellent rigidity with thermal stability and low friction generation. It also has low water retention and good chemical resistance. 

However, mold shrinkage is high for POM resins, and they cannot resist UV rays in sunlight. They also cannot be fire-rated to safety standards.

Because of these qualities, they are suitable for products like bearings, gears, pulley wheels, fasteners, lock systems, conveyor belts, and high-performance engineering components.

Polypropylene (PP)

Polypropylene (PP) is the second most common plastic material in the world. It has similar properties to polyethylene (PE) but has slightly improved hardness and heat resistance. It also has the lowest density — though that can be changed with the use of fillers. 

PP plastics feature good chemical resistance, a high melting point, and resistance to torsion and bending. They are also resistant to water, so they won’t degrade. It is also recyclable up to four times. 

However, PP is extremely degradable under UV light and is also very flammable. When burnt, it produces gasses that are harmful to humans. PP is also difficult to bond, hence it is difficult to paint — but pigments can be added to change color. 

PP applications include a variety of consumer, commercial and industrial products, including storage containers, plastic packaging, appliance components, and power tool bodies.

Polystyrene (PS)

Polystyrene (PS) is a commodity plastic and is known to be a brittle material. However, it can be compounded with additives such as butadiene rubber to improve its dimensional stability.

PS can be either opaque or have glass-like clarity, depending on which type of PS you choose. PS is also well-suited for injection molding projects, as it has a predictable and uniform shrink rate. They are also inexpensive, lightweight, and resistant to moisture and bacteria growth — making them a cost-effective material for certain applications. 

The downside to PS is that it is flammable, not UV ray resistant, and will degrade when exposed to hydrocarbon solvents such as benzene and kerosene. And, due to its brittleness, it is prone to cracking. It is also a non-biodegradable plastic. 

PS is often used for medical, optical, and electrical products. With additives, PS is a good option for appliances and equipment.

Thermoplastic Elastomer (TPE)

TPE, also known as thermoplastic rubber (TPR), is a blend of plastic and rubber. It performs like rubber but is processed like plastic. It offers elasticity, which allows it to be stretched without losing its original shape. It also has shorter molding cycles, which makes TPE an easy and inexpensive option compared to liquid silicone rubbers.

The downside to them is that they are susceptible to creep, which is when a solid material deforms permanently. TPE may also lose its rubber-like properties at higher temperatures. This material is also more expensive, compared to other plastic resins.

TPE is most often used to make footwear, medical equipment (such as breathing tubes and valves), auto components (such as weather seals), and pet products. 

Thermoplastic Polyurethane (TPU) 

Lastly, TPU: a type of thermoplastic elastomer. Similar to TPE, it has a rubber-like elasticity but is more durable. As a result, it is a good replacement for hard rubber materials. 

Unlike TPE, TPU performs better under extreme temperatures and has enhanced chemical resistance. It also has better resistance to loads, abrasion, chemicals, and grease. 

However, it is more rigid and hard than TPE. It may be too hard for some injection molded parts. It also comes with a high price tag — and drying is required before injection molding, making the process expensive. 

TPE applications include footwear, automotive components (such as gaskets), sporting goods, enclosures for electronics, and medical devices. In some cases, they can be used to replace PVC.

Key Takeaway

This brief overview of common injection molding materials covers some of the key characteristics of these resins, which should help you narrow your list of possible material options. 

You can also explore your material selection process with a trusted plastic injection molding company in China, like Richfields! Our team is always ready to collaborate with you on your plastic project — message us here, and we can help you find the perfect resin to suit your unique project needs.

What is the best plastic for making molds?

10 Most Popular Injection Molding Materials